Blar i forfatter "Papaefthymiou, Georgia C."

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    • A thermally stable {FeNO}(8) complex: properties and biological reactivity of reduced MNO systems 

      Patra, Ashis K.; Dube, Koustubh S.; Sanders, Brian C.; Papaefthymiou, Georgia C.; Conradie, Jeanet; Ghosh, Abhik; Harrop, Todd C. (Journal article; Tidsskriftartikkel; Peer reviewed, 2012-10-06)
      Reduced nitrogen oxide ligands such as NO<sup>−</sup>/HNO or nitroxyl participate in chemistry distinct from nitric oxide (NO). Nitroxyl has been proposed to form at heme centers to generate the Enemark–Feltham designated {FeNO}<sup>8</sup> system. The synthesis of a thermally stable {FeNO}<sup>8</sup> species namely, [Co(Cp<sup>*</sup>)<sub>2</sub>][Fe(LN<sub>4</sub>)(NO)] (3), housed in a heme-like ...